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Potassium thiocyanate

Posted: 27 Jun 2013, 18:19
by vlclabbie
Hey guys,

Does anyone have a recipe to make up 1L of 1M Fe(SCN)2+ ?? I did it last year & now can't find my recipe!

I know I didn't use a stock chemical for it & I remember it involving making up 2 vats of chemicals to then mix to make a third..... I think!!!!

Thanks so much if you can help!

Cheers Kel

Re: Potassium thiocyanate

Posted: 09 Jul 2013, 11:00
by Graham Kemp
:mail:
You just need to add 1 mole KSCN to 1 mole Fe(NO3)3 in an acidic solution (use nitric) and dilute to volume. Then store away from light.

The acid keeps the Fe{3+} ions stable and prevents the formation of Fe(OH){2+}. The thiocyanateiron complex will form in an equilibrium reaction; a blood red colour should form. It's the classic qualatively test for the presence of iron(III) in solution.

Re: Potassium thiocyanate

Posted: 15 Jul 2013, 09:06
by Jazz

Re: Potassium thiocyanate

Posted: 17 Jul 2013, 15:41
by mtg
where does the Potassium go?

Re: Potassium thiocyanate

Posted: 18 Jul 2013, 08:38
by Graham Kemp
mtg wrote:where does the Potassium go?
Nowhere. The potassium ions remain in solution.